Synthesis, spectroscopic and electrochemical studies of novel transition metal complexes with N,N '-bis(2-hydroxynaphthalin-1-carbaldehydene)-1,3-bis-(o-aminophenoxy)propane

Temel, HAMDİ; Ilhan, Salih; Aslanoglu, Mehmet; Alp, Huseyin

Synthesis, spectroscopic and electrochemical studies of novel transition metal complexes with N,N '-bis(2-hydroxynaphthalin-1-carbaldehydene)-1,3-bis-(o-aminophenoxy)propane

Temel H., Ilhan S., Aslanoglu M., Alp H.

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, cilt.46, sa.7, ss.1109-1112, 2007 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 46 Sayı: 7
Basım Tarihi: 2007
Dergi Adı: INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.1109-1112
Yozgat Bozok Üniversitesi Adresli: Evet

Özet

A novel Schiff base obtained by the reaction of 1,3-bis-(oaminophenoxy)propane and 2-hydroxynaphthalin-1-carbaldehyde, forms complexes with Co(II), Cu(II) and Ni(II). The Schiff base ligand and its metal complexes have been characterized by elemental analysis, microanalytical data, magnetic measurements, UV-visible, H-1 NMR, C-13 NMR and IR-spectra as well as conductance measurements. Electrochemical data show that NiL and CuL complexes undergo metal based quasi-reversible one-electron redox processes. However, metal complexes also exhibit ligand based irreversible redox waves. The electrochemical results also indicate that the electron transfer rate is higher for NiL complex than the CuL complex. Voltammetric data reveal easier electron donor properties for the NiL complex.