Spectroscopic and electrochemical studies of transition metal complexes with N,N '-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane and structure effects on extractability of ligand towards some divalent cations

Temel H., Alp H., Ilhan S., Ziyadanogullari B., Yılmaz İ.

MONATSHEFTE FUR CHEMIE, vol.138, no.12, pp.1199-1209, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 138 Issue: 12
  • Publication Date: 2007
  • Doi Number: 10.1007/s00706-007-0713-3
  • Journal Name: MONATSHEFTE FUR CHEMIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1199-1209
  • Keywords: thio Schiff base, transition metal complexes, extraction, electrochemical studies, SCHIFF-BASE, ZN(II) COMPLEXES, COPPER(II), NICKEL(II), NI(II), CU(II), MACROCYCLES, EXTRACTION
  • Yozgat Bozok University Affiliated: Yes

Abstract

La(III), Cu(II), Ni(II), and Zn(II) metal complexes with a novel quadridentate Schiff base derived from 1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane and 2-aminothiophenol were synthesized and characterized by microanalytical data, elemental analysis, magnetic measurements, H-1 NMR, C-13 NMR, UV-Vis, IR, mass spectra, cyclic voltammetric and conductance measurements. The extractability of divalent cations was evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. The highest extraction percentage of Cu2+ and Ni2+ showed pH 7.0 and 6.4. It was concluded that the ligand can effectively be used in solvent extraction of copper(II) and nickel(II) from the aqueous phase to the organic phase.