Synthesis and characterization of new macrocyclic Cu(II) complexes from various diamines, copper(II) nitrate and 1,4-bis(2-formylphenoxy)butane

Ilhan S., Temel H., Kilic A.

CHINESE JOURNAL OF CHEMISTRY, cilt.25, sa.10, ss.1547-1550, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 25 Sayı: 10
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1002/cjoc.200790284
  • Dergi Adı: CHINESE JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1547-1550
  • Anahtar Kelimeler: macrocyclic Schiff base complex, 1,4-bis(2-formylphenoxy)butane, diamine, copper(II) complex, TEMPLATE SYNTHESIS, METAL-COMPLEXES, SCHIFF-BASES, NICKEL(II), LIGANDS, TETRADENTATE, LANTHANIDES, DESIGN
  • Yozgat Bozok Üniversitesi Adresli: Evet

Özet

ySix new macrocyclic complexes were synthesized by a template reaction of 1,4-bis(2-formylphenoxy)butane with diamines and Cu(NO3)(2 center dot)3H(2)O and their structures were proposed on the basis of elemental analysis, FT-IR, UV-Vis, magnetic susceptibility measurements, molar conductivity measurements and mass spectra. The metal to ligand molar ratios of the Cu(II) complexes were found to be 1 : 1. The Cu(II) complexes are I : 2 electrolytes as shown by their molar conductivities (A.) in DMF at 10(-3) mol center dot L-1. Due to the existence of free ions the Cu(II) complexes are electrically conductive. Their configurations were proposed to be probably distorted octahedral.