Novel cyclohexyl-based aminophosphine ligands and use of their Ru(II) complexes in transfer hydrogenation of ketones
APPLIED ORGANOMETALLIC CHEMISTRY, cilt.28, sa.2, ss.127-133, 2014 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 28 Sayı: 2
- Basım Tarihi: 2014
- Doi Numarası: 10.1002/aoc.3096
- Dergi Adı: APPLIED ORGANOMETALLIC CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.127-133
- Anahtar Kelimeler: aminophosphine, ruthenium(II), transfer hydrogenation, homogeneous catalysis, ASYMMETRIC TRANSFER HYDROGENATION, ENANTIOSELECTIVE TRANSFER HYDROGENATION, CATALYZED TRANSFER HYDROGENATION, TRANSITION-METAL-COMPLEXES, X-RAY-STRUCTURE, AROMATIC KETONES, C-H, STEREOSELECTIVE HYDROGENATION, ORGANOMETALLIC CHEMISTRY, RUTHENIUM(II) COMPLEXES
- Yozgat Bozok Üniversitesi Adresli: Hayır
Özet
Two new aminophosphines - furfuryl-(N-dicyclohexylphosphino)amine, [Cy2PNHCH2-C4H3O] (1) and thiophene-(N-dicyclohexylphosphino)amine, [Cy2PNHCH2-C4H3S] (2) - were prepared by the reaction of chlorodicyclohexylphosphine with furfurylamine and thiophene-2-methylamine. Reaction of the aminophosphines with [Ru((6)-p-cymene)(-Cl)Cl](2) or [Ru((6)-benzene)(-Cl)Cl](2) gave corresponding complexes [Ru(Cy2PNHCH2-C4H3O)((6)-p-cymene)Cl-2] (1a), [Ru(Cy2PNHCH2-C4H3O)((6)-benzene)Cl-2] (1b), [Ru(Cy2PNHCH2-C4H3S)((6)-p-cymene)Cl-2] (2a) and [Ru(Cy2PNHCH2-C4H3S)((6)-benzene)Cl-2] (2b), respectively, which are suitable catalyst precursors for the transfer hydrogenation of ketones. In particular, [Ru(Cy2PNHCH2-C4H3S)((6)-benzene)Cl-2] acts as a good catalyst, giving the corresponding alcohols in 98-99% yield in 30min at 82 degrees C (up to time of flight588h(-1)). Copyright (c) 2014 John Wiley & Sons, Ltd.