Genesis of Tertiary Akçakışla vein-type Pb-Zn-Cu mineralisation (Central Anatolia, Turkey): Evidence from fluid inclusion and O, H, S, Pb-isotope compositions


Ünal Çakır E., Gökce A., Harris C.

Journal of African Earth Sciences, cilt.205, 2023 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 205
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1016/j.jafrearsci.2023.105008
  • Dergi Adı: Journal of African Earth Sciences
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aquatic Science & Fisheries Abstracts (ASFA), CAB Abstracts, Geobase, INSPEC
  • Anahtar Kelimeler: Akçakışla-Akdağmadeni, Fluid inclusion, Isotope geochemistry, Lead–zinc–copper deposit
  • Yozgat Bozok Üniversitesi Adresli: Evet

Özet

The Akçakışla Pb–Zn–Cu vein type deposit is one of the active mining deposits located in the Akdağmadeni (Yozgat) metallogenic province in Turkey. The sulfide vein deposit, trending E-W, is hosted by calcschist of the Akçakışla and Topaktaş formations of Akdağmadeni metamorphites, which are intruded by the Central Anatolian granitoids and overlain by sedimentary and Tertiary volcanic rocks. Microthermometric measurements indicate that the Pb-Zn-Cu deposit formed by hydrothermal fluids containing dissolved CaCl2, MgCl2 and NaCl. A mixing of fluids with greatly varying salinities and temperatures is shown by the wide range of calculated salinity (0.2–10.4%) and temperature (170–400 °C) values. Isotope ratios of oxygen (δ18OH2O = −5.09 to +4.71‰) and hydrogen (δD = −67‰ and −82‰) suggest that water in hydrothermal fluid might be either mixing of meteoric and magmatic waters or meteoric water that oxygen isotope composition was modified by fluid-rock interaction. Sulphide minerals exhibit δ34S values ranging from 5.51‰ to 8.40‰, which assume a magmatic sulphur source modified by assimilation of upper crustal material (possibly the host metamorphites). In galena from the studied Akçakışla Pb–Zn–Cu deposit ratios of 206Pb/204Pb (18.783–18.821),207Pb/204Pb (15.654–15.700) and 208Pb/204Pb (38.874–39.039) suggest a mixture of lead sources from orogenic-upper crust materials. We assume that hydrothermal fluids dissolved the sulphur from the intruded granitoids and the lead from the host metamorphites. The galena Pb model ages values point out two different ore forming ages; suggesting initial formation in upper Cretaceous (87 Ma) and highly reworking in Eocene–Oligocene (23 and 39 Ma).