BIS(N,N '-BIS(2-HYDROXYETHYL)ETHYLENEDIAMINE)NICKEL(II) SACCHARINATE: SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE


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Karadogan A., KARADAĞ A. , YILMAZ V. T.

MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING, vol.34, no.1, pp.101-104, 2015 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 34 Issue: 1
  • Publication Date: 2015
  • Doi Number: 10.20450/mjcce.2015.651
  • Title of Journal : MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING
  • Page Numbers: pp.101-104

Abstract

A new nickel(II) saccharinate (sac) complex containing N,N'-bis(2-hydroxyethyl)ethylenediamine (bishydeten), [Ni(bishydeten)(2)](sac)(2), has been synthesized and characterized by elemental analysis, FTIR. and single crystal X-ray diffraction. The title complex consists of a [Ni(bishydeten)(2)](2+) cation and two sac anions. In the complex cation, the nickel(II) ion is coordinated by two neutral bishydeten ligands, leading to a distorted octahedral NiN4O2 coordination, while both sac anions remain outside the coordination sphere. In the crystal, the complex cations and sac anions are connected by an extensive network of N-H center dot center dot center dot N, N-H center dot center dot center dot O, O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds into a three-dimensional supramolecular lattice.