Synthesis, characterization, and polymerization of new methacrylate esters having pendant amide moieties


Erol I., Soykan C.

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, vol.39, no.5, pp.405-417, 2002 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 39 Issue: 5
  • Publication Date: 2002
  • Doi Number: 10.1081/ma-120003963
  • Title of Journal : JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
  • Page Numbers: pp.405-417

Abstract

In this paper, the synthesis of a number of new methacrylate esters containing amide group are described. The monomers produced from the reaction of corresponding alpha-chloro-N-aryl or -N-alkyl acetamides with sodium methacrylate were polymerized with AIBN as initiator. The monomers and their polymers were characterized by IR, H-1- and C-13-NMR spectroscopy. The glass transition temperature and thermal decomposition temperature of the polymers were investigated by DSC-50 and TGA-50 thermobalance, respectively. The photocrosslinking properties of the polymers were also discussed.