Synthesis, characterization, and polymerization of new methacrylate esters having pendant amide moieties
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, cilt.39, sa.5, ss.405-417, 2002 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 39 Sayı: 5
- Basım Tarihi: 2002
- Doi Numarası: 10.1081/ma-120003963
- Dergi Adı: JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.405-417
- Yozgat Bozok Üniversitesi Adresli: Hayır
Özet
In this paper, the synthesis of a number of new methacrylate esters containing amide group are described. The monomers produced from the reaction of corresponding alpha-chloro-N-aryl or -N-alkyl acetamides with sodium methacrylate were polymerized with AIBN as initiator. The monomers and their polymers were characterized by IR, H-1- and C-13-NMR spectroscopy. The glass transition temperature and thermal decomposition temperature of the polymers were investigated by DSC-50 and TGA-50 thermobalance, respectively. The photocrosslinking properties of the polymers were also discussed.