Preparation, spectra and thermal properties of two novel cyano-bridged complexes: crystal structure of one-dimensional copper(II))/palladium(II)

Karadag A.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, cilt.222, sa.1, ss.39-45, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 222 Sayı: 1
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1524/zkri.2007.222.1.39
  • Dergi Adı: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.39-45
  • Yozgat Bozok Üniversitesi Adresli: Evet

Özet

Two new coordination polymers, {-M(hydeten)(2)-NC-Pd(CH)(2)-CN}(n), [M = Ni and Cu, hydeten; N-(2-hydroxyethyl)-ethylenediamine)], have been synthesized and their elemental, thermal and spectroscopic (IR and UV-vis) properties have been studied. The crystal structure analysis of the Cu-Pd complex has indicated a polymeric chain -Cu(hydeten)(2)-NC-Pd(CN)(2)Cu(hydeten)(2)- in which the Pd(II) ions are four-coordinated by carbon atoms from four cyano groups in a square-planar arrangement, whereas Cu(II) ions are six-coordinated with two cis cyano N and four N atoms of bidentate hydeten ligands in a distorted octahedral arrangement.