The synthesis and spectral characterization of new Cu(II), Ni(II), Co(III), and Zn(II) complexes with Schiff base

Temel H., Ilhan S., Sekerci M., Ziyadanogullari R.

SPECTROSCOPY LETTERS, cilt.35, sa.2, ss.219-228, 2002 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 35 Sayı: 2
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1081/sl-120003807
  • Dergi Adı: SPECTROSCOPY LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.219-228
  • Anahtar Kelimeler: Schiff bases, transition metals, METAL-COMPLEXES, COPPER(II)
  • Yozgat Bozok Üniversitesi Adresli: Evet

Özet

Cu(II), Ni(II), Co(III) and Zn(II) complexes with Schiff base have been prepared. Ligand is derived from condensation of 1,2-bis(p-aminophenoxy)ethane and 2-hydroxynaphthalin-1-carbaldehyde. The complexes have been characterized by elemental analyses, Lambda(M), IR, UV-VIS, H-1 NMR, C-13 NMR and magnetic measurements. The ligand is coordinated to the central metal as a tetradentade ONNO ligand. The four bonding sites are the azomethine nitrogen and aldehydic-OH groups.