The synthesis and spectral characterization of new Cu(II), Ni(II), Co(III), and Zn(II) complexes with Schiff base


Temel H. , Ilhan S., Sekerci M., Ziyadanogullari R.

SPECTROSCOPY LETTERS, vol.35, no.2, pp.219-228, 2002 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 35 Issue: 2
  • Publication Date: 2002
  • Doi Number: 10.1081/sl-120003807
  • Title of Journal : SPECTROSCOPY LETTERS
  • Page Numbers: pp.219-228
  • Keywords: Schiff bases, transition metals, METAL-COMPLEXES, COPPER(II)

Abstract

Cu(II), Ni(II), Co(III) and Zn(II) complexes with Schiff base have been prepared. Ligand is derived from condensation of 1,2-bis(p-aminophenoxy)ethane and 2-hydroxynaphthalin-1-carbaldehyde. The complexes have been characterized by elemental analyses, Lambda(M), IR, UV-VIS, H-1 NMR, C-13 NMR and magnetic measurements. The ligand is coordinated to the central metal as a tetradentade ONNO ligand. The four bonding sites are the azomethine nitrogen and aldehydic-OH groups.