[N-(2-Hydroxyethyl)ethylenediamine-kappa N-3,N ',O]-cis-bis(isothiocyanato-kappa N)-copper(II)


Pasaoglu H., Karadag A. , Tezcan F., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, vol.61, 2005 (Journal Indexed in SCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 61
  • Publication Date: 2005
  • Doi Number: 10.1107/s0108270104033803
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY

Abstract

In the novel transition metal isothiocyanate complex of N-(2-hydroxyethyl)ethylenediamine (hydet-en) with copper, [Cu(NCS)(2)(C4H12N2O)], the Cu atom lies in a distorted square-pyramidal environment, coordinated by four N atoms in the basal plane and an apical O atom. The hydet-en ligand is N,N,O-tridentate, in contrast to the disposition in previously studied complexes, while the isothiocyanate ions act as N-atom donor ligands. The monomeric units are linked to one another by hydrogen bonds.