Structure and characterization of methyl (+/-)-1-(2-aminophenyl)-2-hydroxy-4-(4-methomybenzoyl)-5-(4-methoxyphenyl)-3-oxo-2,3-dihydro-1H-pyrrole-2-acetate


Arici C., Ulku D., Ungoren S., Sacmaci M., Akcamur Y.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, vol.219, no.9, pp.554-557, 2004 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 219 Issue: 9
  • Publication Date: 2004
  • Doi Number: 10.1524/zkri.219.9.554.44037
  • Title of Journal : ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Page Numbers: pp.554-557

Abstract

The stoichiometry of I was derived from the results of elemental analysis, IR, H-1, C-13-NMR, UV-Vis and mass spectroscopic techniques. The structure derived from physico-chemical methods is consistent with that of the X-ray diffraction. The compound crystallizes in the triclinic system, space group P (1) over bar, with a = 9.3895(12), b = 11.3759(11), c = 12.8077(14) Angstrom, alpha = 103.290(3)degrees beta = 98.110(4)degrees, gamma = 105.545(3)degrees, V = 1252.4(2) Angstrom(3), Z = 2. The molecule has a non-planar configuration. The methoxycarbonylmethyl group exhibits an E-configuration. The crystal structure is stabilized by intermolecular C-H...O, N-H...O and O-H...O contacts.