Photochemical reactions of metal carbonyls [M(CO)(6) (M=Cr, Mo, W)] with N,N '-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane

SUBAŞI E., Temel H., Senturk O. S., Ugur F.

JOURNAL OF COORDINATION CHEMISTRY, vol.59, no.16, pp.1807-1811, 2006 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 59 Issue: 16
  • Publication Date: 2006
  • Doi Number: 10.1080/00958970600571703
  • Journal Name: JOURNAL OF COORDINATION CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1807-1811
  • Keywords: N,N '-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane, metal carbonyls, Schiff base, ZN(II) COMPLEXES, PR-N, RE(CO)(5)BR, MANGANESE(III), EPOXIDATION, COPPER(II), ZINC(II), LIGANDS, OLEFINS, CU(II)
  • Yozgat Bozok University Affiliated: Yes

Abstract

The complexes [M(CO)(4)(eta(2)-H2L)][M Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)(6)] [M Cr, Mo, W] with N, N'-bis(salicylidene)-1,2-bis-(o-aminophenoxy) ethane (H2L) in THF and characterized by elemental analyses, FTIR, (HNMR)-H-1 and mass spectra. The H2L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.