Novel Hg(II) and Pd(II) benzotriazole (Hbta) complexes: Synthesis, characterization, X-ray crystal structure of [Pd(PPh3)(mu-bta)Cl](2)center dot DMSO and thermodynamic study of their H-2 storage


Al-Jibori S. A. , Al-Doori L. A. , Al-Janabi A. S. M. , Alheety M. A. , AKBAŞ H., KARADAĞ A.

JOURNAL OF MOLECULAR STRUCTURE, vol.1207, 2020 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 1207
  • Publication Date: 2020
  • Doi Number: 10.1016/j.molstruc.2020.127832
  • Title of Journal : JOURNAL OF MOLECULAR STRUCTURE

Abstract

Benzotriazole (Hbta) complexes with Hg(II) and Pd(II) of the types: [Hg(bta)2] (1), [Hg(bta)(2)(diphos)]; diphos = dppe (2), dppp (3) or dppb (4), [Hg(bta)(2)(PPh3)(2)] (5), [Pd(Hbta)(2)Cl-2] (6), [Pd(bta)Cl](2) (7) and [PdCl(bta)(PPh3)](2)center dot DMSO (8) were prepared and characterized by elemental analyses, conductivity measurements, infrared, H-1- and P-31-{H-1} NMR spectra.