Dynamic H-1 NMR Studies of Schiff Base Derivatives

Koylu M. Z., Ekinci A., BÖYÜKATA M., Temel H.

JOURNAL OF APPLIED SPECTROSCOPY, cilt.82, sa.6, ss.905-909, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 82 Sayı: 6
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1007/s10812-016-0202-8
  • Dergi Adı: JOURNAL OF APPLIED SPECTROSCOPY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.905-909
  • Yozgat Bozok Üniversitesi Adresli: Evet

Özet

The spin-lattice relaxation time T (1) and the spin-spin relaxation time T (2) of two Schiff base derivatives, N,N'-ethylenebis(salicylidene)-1,2-diaminoethane (H2L1) and N,N'-ethylenebis (salicylidene)-1,3-diaminopropane (H2L2), in DMSO-d(6) solvent were studied as a function of temperature in the range of 20-50A degrees C using a Bruker Avance 400.132 MHz H-1 NMR spectrometer. Based on the activation energy (E (a)) and correlation time (tau(c)), we believe that the Schiff base derivatives perform a molecular tumbling motion.