A New Preconcentration Method for the Determination of Pb and Ni in Real Samples by Using Amberlite XAD-16 Functionalized With 1,6-bis(2-carboy aldehyde phenoxy)butane

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Oral E. V., Erdogan S., Temel H., Ziyadanogullari B., Ziyadanogullari R.

ATOMIC SPECTROSCOPY, vol.40, no.3, pp.104-112, 2019 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 40 Issue: 3
  • Publication Date: 2019
  • Doi Number: 10.46770/as.2019.03.005
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.104-112
  • Yozgat Bozok University Affiliated: No


In this study, a steady chelating resin matrix was formed by tying 1,6-bis(2-carboxy aldehyde phenoxy) butane to Amberlite XAD-16 resin by a -C=N- group. This synthesized adsorbent was placed into a minicolumn to separate and preconcentrate the lead and nickel ions before their determination by flame atomic absorption spectrometry (PARS). The effects of many parameters on the preconcentration method were examined. The optimal pH value for the quantitative absorption of lead and nickel was pH 5.0. The percentage of recovery for lead and nickel was 99 +/- 1.15% and 100 +/- 2.70%, respectively. The detection limits of lead and nickel utilizing FAAS (3s, N=20) were 1.47 and 1.16 mu g/L, respectively. The effects of some matrix components on the recovery were analyzed. The suggested method was utilizied to determine lead and nickel in real water samples obtained from the River Tigris in Turkey, as well as in automobile exhaust particles, Romaine letnice, and parsley. The accuracy of the proposed method was verified by using the standard addition method and the standard reference material NCS-DC 73350 Poplar Leaves.