Synthesis and characterization of Na+, K+, Ca2+, Ba2+, Sr2+, and Pb2+ complexes with some lipophilic diaza-18-crown-6 derivatives

Temel H., Hosgoren H., Boybay M.

SPECTROSCOPY LETTERS, cilt.35, sa.1, ss.1-8, 2002 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 35 Sayı: 1
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1081/sl-120013128
  • Dergi Adı: SPECTROSCOPY LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1-8
  • Anahtar Kelimeler: IR, H-1/C-13 NMR diazamacrocycles, metal complexes, CROWN, ETHERS
  • Yozgat Bozok Üniversitesi Adresli: Evet

Özet

In this study, the complexes of 7,16-Dibenzyl-4,7,10,13-tetraoxa-7,16-diazacyclooctadecane; 7,16-Dihexzyl-4,7,10,13tetraoxa-7,16-diazacyclooctadecane; 7,16-Diheptyl-4,7,10,13tetraoxa-7,16-diazacyclooctadecane; 7,16-Dioctyl-4,7,10,13tetraoxa-7,16-diazacyclooctadecane; 7,16-Dinonyl-4,7,10,13tetraoxa-7,16-diazacyclooctadecane; 7,16-Didodecyl 4,7,10, 13-tetraoxa-7,16-diazacyclooctadecane with Na+, K+, Ca2+, Ba2+, Sr2+ and Pb2+ were prepared by using perchlorates salts. Their complexes were produced by adding the solution of metal salts in ethyl alcohol to the solution of ligand in ethyl alcohol. The complexes obtained were filtered and washed with ethyl alcohol and recrystallizied in ethyl alcohol and dried in vacuum. Their complexes were investigated by using Elemental Analysis, and infrared (IR). Observed H-1 NMR,C-13 NMR, and C-13 chemical shifts are discussed in terms of conformational changes of the macrocycle.