Synthesis of new lariat cyclicdiamides and their metal complexes

Cakir U., Karakaplan M., Temel H., Hosgoren H., Erk C.

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, cilt.26, sa.1-3, ss.21-26, 1996 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 26 Sayı: 1-3
  • Basım Tarihi: 1996
  • Doi Numarası: 10.1007/bf01029924
  • Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.21-26
  • Anahtar Kelimeler: macrocylic diazadioxo ethers, cation complexation, ETHERS
  • Yozgat Bozok Üniversitesi Adresli: Evet

Özet

Three new lariat dilactam host molecules were prepared by the reaction of triethyleneglycol dicarboxylic acid dichloride with N, N'-disubstituted-4, 7-dioxa-1, 10-diazadecane precursors. The amide nitrogen pivot of such compounds are substituted with the benzyl, octyl and dodecyl groups. The complexing ability of these dilactams is displayed with a series of metal complexes of Na+, K+, Ca2+, Sr2+, Pb2+ and Ag+ ions. The structures determined are consistent with the data of H-1-NMR, C-13-NMR, IR spectra and elemental analyses.