Synthesis of new lariat cyclicdiamides and their metal complexes

Cakir, U; Karakaplan, M; Temel, HAMDİ; Hosgoren, H; Erk, C

doi:10.1007/bf01029924

Synthesis of new lariat cyclicdiamides and their metal complexes

Cakir U., Karakaplan M., Temel H., Hosgoren H., Erk C.

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, cilt.26, sa.1-3, ss.21-26, 1996 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 26 Sayı: 1-3
Basım Tarihi: 1996
Doi Numarası: 10.1007/bf01029924
Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.21-26
Anahtar Kelimeler: macrocylic diazadioxo ethers, cation complexation, ETHERS
Yozgat Bozok Üniversitesi Adresli: Evet

Özet

Three new lariat dilactam host molecules were prepared by the reaction of triethyleneglycol dicarboxylic acid dichloride with N, N'-disubstituted-4, 7-dioxa-1, 10-diazadecane precursors. The amide nitrogen pivot of such compounds are substituted with the benzyl, octyl and dodecyl groups. The complexing ability of these dilactams is displayed with a series of metal complexes of Na+, K+, Ca2+, Sr2+, Pb2+ and Ag+ ions. The structures determined are consistent with the data of H-1-NMR, C-13-NMR, IR spectra and elemental analyses.