Synthesis and complexation of new substituted dibenzodiaza macrocyclic diester compounds


Topal G., Temel H. , Cakir U., Ugras H., Karadeniz F., Hosgoren H.

SYNTHETIC COMMUNICATIONS, vol.32, no.11, pp.1721-1729, 2002 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 32 Issue: 11
  • Publication Date: 2002
  • Doi Number: 10.1081/scc-120004267
  • Title of Journal : SYNTHETIC COMMUNICATIONS
  • Page Numbers: pp.1721-1729
  • Keywords: diazacrowns, dibenzodiazacrowns, oligoethylene glycols, derivatives, synthesis, complexation constant, conductometry, CROWN

Abstract

The synthesis of some new precoursers that contain substituted benzo units and their use in the preparation of azama-crocyclic diester compounds are reported. These precoursers and ligands were characterized by Elemental analysis, H-1 and C-13 NMR spectroscopy, and IR spectroscopy. The complexation constants Ke and DeltaGdegrees values for the diesters with several transition metal cations (Ag+, Zn2+ and Cu2+) in a dioxan-water system using a conductometric method at 25degreesC are also reported.