Synthesis, structural characterization of new macrocyclic Schiff base derived from 1,6-bis(2-formylphenyl)hexane and 2,6-diaminopyridine and its metal complexes

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Atıf İçin Kopyala

Ilhan S., Ternel H., Sunkur M., Tegin I.

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, cilt.47, sa.4, ss.560-564, 2008 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 47 Sayı: 4
• Basım Tarihi: 2008
• Dergi Adı: INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.560-564
• Yozgat Bozok Üniversitesi Adresli: Hayır

Özet

A macrocyclic ligand has been synthesized by reaction of 2,6-diaminopyridine and 1,6-bis(2-formylphenyl).hexane. Its complexes with Cu(II), Ni(II), Pb(II), Zn(II), Cd(II) and La(III) have been synthesized by the reaction of ligand and Cu(ClO4)(2)center dot 6H(2)O, Ni(ClO4)(2)center dot 6H(2)O, Pb(ClO4)(2)center dot 6H(2)O, Zn(ClO4)(2)center dot 6H(2)O, Cd(ClO4)(2)center dot 6H(2)O and La(ClO4)(3)center dot 6H(2)O, respectively. The ligand and its metal complexes have been characterized. All complexes are diamagnetic while the Cu(II) complex is binuclear.