Novel self-condensation of ammonium dithiocarbamates leading to symmetrical substituted thioureas

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Atıf İçin Kopyala

ÜNGÖREN Ş. H., Sirca F.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.192, sa.1, ss.28-33, 2017 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 192 Sayı: 1
• Basım Tarihi: 2017
• Doi Numarası: 10.1080/10426507.2016.1223075
• Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.28-33
• Yozgat Bozok Üniversitesi Adresli: Evet

Özet

For the first time, the formation of symmetrical substituted thiourea analogues generated by the self-condensation of trialkylammoniumdithiocarbamates is reported. The reactions occurred under mild conditions. The method allows the use of amines possessing a weak nucleophilic feature in good yields. The highlight of the study is a novel self-condensation mechanism based on dithiocarbamates as a basic compound in organic chemistry.